snopes.com: Reuse of Plastic Bottles
snopes.com: Reuse of Plastic Bottles.
From the 13 April 2004 article
….such claims are inaccurate on two counts: DEHA is not used in the manufacture of PET bottles (nor is it created through the breakdown of such bottles), and DEHA is not classified as a human carcinogen:
DEHA is neither regulated nor classified as a human carcinogen by the U.S. Occupational Safety & Health Administration, the National Toxicology Program or the International Agency for Research on Cancer, the leading authorities on carcinogenic substances.In 1991, on the basis of very limited data, the U.S. Environmental Protection Agency classified DEHA as a “possible human carcinogen.” However, in 1995, EPA again evaluated the science and concluded that ” … overall, the evidence is too limited to establish that DEHA is likely to cause cancer.”
Further, DEHA is not inherent in PET as a raw material, byproduct or decomposition product.
Moreover, DEHA has been cleared by FDA for food-contact applications and would not pose a health risk even if it were present.
Finally, in June 2003, the Swiss Federal Laboratories for Materials Testing and Research conducted a scientific study of migration in new and reused plastic water bottles from three countries. The Swiss study did not find DEHA at concentrations significantly above the background levels detected in distilled water, indicating DEHA was unlikely to have migrated from the bottles. The study concluded that the levels of DEHA were distinctly below the World Health Organization guidelines for safe drinking water.
The American Cancer Society also debunked such claims, stating:
In fact, DEHA is not inherent in the plastic used to make these bottles, and even if it was the U.S. Environmental Protection Agency (EPA) says DEHA “cannot reasonably be anticipated to cause cancer, teratogenic effects, immunotoxicity, neurotoxicity, gene mutations, liver, kidney, reproductive, or developmental toxicity or other serious or irreversible chronic health effects.” Meanwhile, the International Agency for Research on Cancer (IARC), says diethylhexyl adipate “is not classifiable as to its carcinogenicity to humans.”As for the notion that freezing water in plastic bottles releases dioxin, the American Chemical Council asserted:
There simply is no scientific basis to support the claim that PET bottles will release dioxin when frozen. Dioxins are a family of chemical compounds that are produced by combustion at extremely high temperatures. They can only be formed at temperatures well above 700 degrees Fahrenheit; they cannot be formed at room temperature or in freezing temperatures. Moreover, there is no reasonable scientific basis for expecting dioxins to be present in plastic food or beverage containers in the first place.Johns Hopkins researcher Dr. Rolf Halden also said of such claims that:
Q: What do you make of this recent email warning that claims dioxins can be released by freezing water in plastic bottles?A: This is an urban legend. There are no dioxins in plastics. In addition, freezing actually works against the release of chemicals. Chemicals do not diffuse as readily in cold temperatures, which would limit chemical release if there were dioxins in plastic, and we don’t think there are.
Dr. Halden did note that drinking water from plastic bottles that had been exposed to high temperatures could be problematic, though:
There is another group of chemicals, called phthalates that are sometimes added to plastics to make them flexible and less brittle. Phthalates are environmental contaminants that can exhibit hormone-like behavior by acting as endocrine disruptors in humans and animals. If you heat up plastics, you could increase the leaching of phthalates from the containers into water and food.Another common type of plastic bottle is made with bisphenol A, also known as BPA. These products are typically rigid plastic bottles intended for multiple re-use, such as baby bottles or water bottles carried by cyclists. Concerns about tests that may link BPA ingestion with cancer and reproductive damage in some animals and the possibility that BPA could leach out of plastic bottles and into the liquids they contain has led to bans on the use of BPA in plastic products intended for children (such as baby bottles), and has prompted some consumers to seek out non-BPA alternatives.
Read more at http://www.snopes.com/medical/toxins/plasticbottles.asp#uD3X2UPBl0L8LhsG.99